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Question

The method by which aniline cannot be prepared is:

Nitration of benzene followed by reduction with $Sn$ and concentrated $HCl$

Degradation of benzamide with bromine in an alkaline solution

Reduction of nitrobenzene with $H_2$/$Pd$ in ethanol

Potassium salt of phthalimide treated with chlorobenzene followed by hydrolysis with aqueous $NaOH$ solution

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