Which of the following has a pH value that is NOT equal to one?
0.1 M $CH_3COOH$
0.1 M $HNO_3$
0.05 M $H_2SO_4$
$50\, \text{cm}^3\, 0.4\, \text{M}\, HCl + 50\, \text{cm}^3\, 0.2\, \text{M}\, NaOH$
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