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Question

The orange colour of $\mathrm{K}_2 \mathrm{Cr}_2 \mathrm{O}_7$ and purple colour of $\mathrm{KMnO}_4$ is due to

Charge transfer transition in both.
$\mathrm{d} \rightarrow \mathrm{d}$ transitions in $\mathrm{KMnO}_4$ and charge transfer transitions in $\mathrm{K}_2 \mathrm{Cr}_2 \mathrm{O}_7$.
$\mathrm{d} \rightarrow \mathrm{d}$ transitions in both
$\mathrm{d} \rightarrow \mathrm{d}$ transitions in $\mathrm{K}_2 \mathrm{Cr}_2 \mathrm{O}_7$ and charge transfer transitions in $\mathrm{KMnO}_4$.

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