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Question

When a solution of mixture having two inorganic salts was treated with freshly prepared ferrous sulphate in acidic medium, a dark brown ring was formed whereas on treatment with neutral $\mathrm{FeCl}_{3}$, it gave deep red colour which disppeared on boiling and a brown red ppt was formed. The mixture contains :

SO$_3^{2-}$ & C$_2$O$_4^{2-}$
$\mathrm{CH}_{3} \mathrm{COO}^{-} \& ~\mathrm{NO}_{3}^{-}$
$\mathrm{C}_{2} \mathrm{O}_{4}{ }^{2-} \& ~\mathrm{NO}_{3}^{-}$
$\mathrm{SO}_{3}^{2-} \& ~\mathrm{CH}_{3} \mathrm{COO}^{-}$

Solution

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