Which of the following sets of quantum numbers is not allowed?
$$
\mathrm{n}=3,1=2, \mathrm{~m}_{\mathrm{l}}=0, \mathrm{~s}=+\frac{1}{2}
$$
$$
\mathrm{n}=3, \mathrm{l}=2, \mathrm{~m}_{\mathrm{l}}=-2, \mathrm{~s}=+\frac{1}{2}
$$
$$
\mathrm{n}=3, \mathrm{l}=3, \mathrm{~m}_{\mathrm{l}}=-3, \mathrm{~s}=-\frac{1}{2}
$$
$$
\mathrm{n}=3, \mathrm{l}=0, \mathrm{~m}_{1}=0, \mathrm{~s}=-\frac{1}{2}
$$
