Presence of which reagent will affect the reversibility of the following reaction, and change it to a irreversible reaction :CH4 + I2 $$\mathrel{\mathop{\kern0pt\rightleftharpoons} \limits_{{\mathop{\rm Re}\nolimits} versible}^{hv}} $ CH3 $-$$ I + HI

Question

Presence of which reagent will affect the reversibility of the following reaction, and change it to a irreversible reaction :

CH₄ + I₂ $$\mathrel{\mathop{\kern0pt\rightleftharpoons} \limits_{{\mathop{\rm Re}\nolimits} versible}^{hv}} $ CH₃ $-$$ I + HI

HOCl

dilute HNO₂

Liquid NH₃

Concentrated HIO₃

Solution

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