Which of the following sets of quantum numbers is correct for an electron in 4f orbital?

Question

n = 4, l = 3, m = +1, s = + 1/2

n = 4, l = 4, m = -4, s = - 1/2

n = 4, l = 3, m = +4, s = + 1/2

n = 3, l = 2, m = -2, s = + 1/2

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